Shape Memory Polymers
Shape memory polymers (SMPS) are thermo-responsive materials
which switch from a temporary shape to a permanent shape by heating above its
transition temperature. The development of this shape memory polymers enables
high recovery stress levels as well as novel functions such as electrical
conductivity, magnetism, and biofunctionality. Dr. Grunlan’s lab is working on
developing shape memory polymers with silicon-containing segments in order to
achieve excellent mechanical properties such as shape fixity, and shape
recovery. SMPs were prepared by
photocuring diacrylated PCLn-block-PDMS37-block-PCLn
macromers with tailored PDMS [polydimethylsiloxane] and PCL
[poly(ε-caprolactone)] segment lengths. Both solid SMPs and shape memory foams
are being studied.
In the biomedical
field, shape memory polymers may permit the development of superior
interventional devices. This technology could help my grandfather potentially
someday. Currently, my grandfather suffers from reoccurring blood clots. The
SMPs can be used for blood clot removal by forming a self-expanding stent.
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